Chocolate Glazed Orange Poppy Seed Cake

Heat oven to 350 °F (175°C). Grease and flour 12 cup Bundt pan or 10-inch tube pan. For Cake: Combine cake mix, poppy seed, milk, eggs, sour cream and orange peel in large bowl; beat until well blended. Pour batter into prepared pan. Bake 40 to 45 minutes or until wooden pick inserted in center comes out clean. Cool 20 minutes; remove from pan to wire rack. Cool completely. For Chocolate Orange Glaze: Melt butter in small saucepan over medium heat. With whisk, stir in cocoa and water until mixture thickens slightly. Remove from heat; stir in liqueur, if desired, orange extract and 1 1/4 cups powdered sugar. Whisk until smooth. If glaze is too thin, whisk in remaining 1/4 cup powdered sugar. Use immediately.; spoon over cake, allowing glaze to run down sides.